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https://github.com/ericchansen/q2mm

Quantum to Molecular Mechanics (Q2MM)
https://github.com/ericchansen/q2mm

force-field-optimization force-fields molecular-mechanics optimal-parameters quantum schrodinger

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Quantum to Molecular Mechanics (Q2MM)

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README

          

# Q2MM

**Quantum-guided molecular mechanics force field optimization.**

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Q2MM optimizes molecular mechanics (MM) force field parameters by minimizing
the difference between MM-calculated properties and quantum mechanics (QM)
reference data. It is designed for building **transition state force fields
(TSFFs)** that enable rapid virtual screening of enantioselective catalysts.

**📖 [Documentation](https://ericchansen.github.io/q2mm/)**

## Why Q2MM?

- **Hessian-informed initialization** — the Seminario method extracts bond and
angle force constants directly from QM Hessians, providing excellent starting
parameters before optimization begins.
- **Open-source backends** — first-class support for [OpenMM](https://openmm.org/)
and [Psi4](https://psicode.org/) alongside commercial packages (Gaussian,
Schrödinger, Tinker).
- **Clean, modular architecture** — format-agnostic data models (`ForceField`,
`Q2MMMolecule`) decouple algorithms from file formats.
- **Modern optimization** — powered by `scipy.optimize` with L-BFGS-B,
Nelder-Mead, trust-region, and Levenberg-Marquardt methods.
- **Transition state support** — negative force constants, torsion parameters,
and proper eigenvalue handling for saddle-point geometries.

## Quick Start

```bash
pip install "q2mm[openmm,optimize]" # OpenMM backend + scipy optimizer
```

> **Pre-release:** the current version is an alpha. Add `--pre` to any
> install command (e.g. `pip install --pre "q2mm[openmm,optimize]"`) if a
> stable release hasn't been published yet.

For development, clone the repo and install in editable mode:

```bash
pip install -e ".[dev]"
```

```python
from q2mm.optimizers.objective import ReferenceData, ObjectiveFunction
from q2mm.optimizers.scipy_opt import ScipyOptimizer
from q2mm.models.seminario import estimate_force_constants
from q2mm.backends.mm import OpenMMEngine

# 1. Load QM reference data and molecule from a Gaussian checkpoint
ref, mol = ReferenceData.from_fchk("ts-optimized.fchk", bond_tolerance=1.4)

# 2. Estimate initial force field from the QM Hessian (Seminario method)
ff = estimate_force_constants(mol, au_hessian=True)

# 3. Set up the objective function and optimize
engine = OpenMMEngine()
obj = ObjectiveFunction(ff, engine, [mol], ref)
result = ScipyOptimizer(method="L-BFGS-B").optimize(obj)

print(result.summary())
```

`ReferenceData.from_fchk()` auto-extracts bond lengths and angles from the
QM geometry. You can also use `from_gaussian()` for `.log` files, or
`from_molecule()` for maximum control. See the
[Tutorial](https://ericchansen.github.io/q2mm/tutorial/) for the full
workflow including frequencies, eigenmatrix data, and multi-molecule fits.

## Supported Backends

| Backend | Type | License |
|---------|------|---------|
| **OpenMM** | MM | MIT |
| **Psi4** | QM | BSD-3 |
| **Tinker** | MM | Free (academic) |
| **Gaussian** | QM | Commercial |
| **Schrödinger** | QM/MM | Commercial |

## License

MIT. See [LICENSE](LICENSE).

## Contributing

See [CONTRIBUTING.md](CONTRIBUTING.md) for development setup, testing with
Docker, and submitting changes.